You have to set UIButton frame your self.
Horizontally Alignment
float X_Co = (self.view.frame.size.width - yourButtonWidth)/2;
[button setFrame:CGRectMake(X_Co, yourYposition, yourButtonWidth, yourButtonheight)];
Vertically Align
float Y_Co = (self.view.frame.size.height - yourButtonheight)/2;
[button setFrame:CGRectMake(yourXposition, Y_Co, yourButtonWidth, yourButtonheight)];
TOP LEFT
[button setFrame:CGRectMake(0.0, 0.0, yourButtonWidth, yourButtonheight)];
TOP RIGHT
float X_Co = self.view.frame.size.width - yourButtonWidth;
[button setFrame:CGRectMake(X_Co, 0.0, yourButtonWidth, yourButtonheight)];
BOTTOM LEFT
float Y_Co = self.view.frame.size.height - yourButtonheight;
[button setFrame:CGRectMake(0.0, Y_Co, yourButtonWidth, yourButtonheight)];
BOTTOM RIGHT
float X_Co = self.view.frame.size.width - yourButtonWidth;
float Y_Co = self.view.frame.size.height - yourButtonheight;
[button setFrame:CGRectMake(X_Co, Y_Co, yourButtonWidth, yourButtonheight)];
Center Of self.view
button.center = self.view.center;
OR
float X_Co = (self.view.frame.size.width - yourButtonWidth)/2;
float Y_Co = (self.view.frame.size.height - yourButtonheight)/2;
[button setFrame:CGRectMake(X_Co, Y_Co, yourButtonWidth, yourButtonheight)];
来自地址:http://stackoverflow.com/questions/12387988/how-to-programmatically-allign-a-button-in-ios-applications